• 82 Downloads • Abstract The kinetics of the initiated oxidation of a model lipid (methyl oleate has been investigated in the presence of a group of new “hybrid” structures, namely, N-substituted amides of salicylic acid whose structure contains an amide residue conjugated with, or separated by a bridging fragment (three methylene groups) from, an N-phenolic substituent. The compounds also differ in the degree of screening of the OH groups. The process was initiated by thermal decomposition of azobisisobutyronitrile at 60°C (initiation rate of w i = 4.2 × 10 −8 mol L −1 s −1) or by UV irradiation (γ = 313−365 nm, w i = 0.6 × 10 −8 mol L −1 s −1). The compounds examined exhibit antiradical activity owing to the presence of the phenolic hydroxyl groups. N-substituted salicylamides efficiently inhibit the overall methyl oleate oxidation process and are comparable in activity with dibunolum and α-tocopherol or are superior to them. The structures in which the residues of salicylamide and sterically hindered phenol are separated by the bridging fragment are particularly efficient.

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The advantages of the salicylamides absorbing at 300–365 nm manifest themselves in UV-initiated oxidation. The peroxidase activity of the N-substituted salicyl acid derivatives is determined by the structure of the amide moiety.

Jan 31, 2018. 7 0.00% 7 0.00%. 1 0.00% 1 0.00%.

The compounds examined here are new, promising, effective antioxidants, whose particular structural fragments act via different mechanisms in oxidation.

• 'Ti' Released: 2006 • 'C'mon Boy' Released: 2006 • 'Nemoj ovako' Released: 2007 Professional ratings Review scores Source Rating Med i mleko ( translation: 'Honey and Milk') is the first solo album from, a performer. It was released in Serbia and in spring 2006. Her first single reached #2 on Top 20 (beaten by 'S 'Crazy'). Her second single, 'C'mon Boy' reached #11 on MTV Adria Top 20.

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However, her third single from the album, 'Nemoj ovako', didn't reach the charts. The third single has been released in January 2007. None of the 3 singles were released as CD singles, but only like videos. Track list [ ] • 'Intro' — 0:39 • 'Ti' — 3:55 • 'C'mon Boy' — 3:16 • 'Lutrija' — 3:22 • 'Nije nam vreme' — 5:29 • 'Da te volim' — 3:21 • 'A.K.' S Black Balls' — 3:37 • 'Love Operator' — 3:33 • 'Nemoj ovako' — 4:52 • 'Ovde ti je dom' — 4:19 References [ ].